Selected Publications
(2014-2025)
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Rohit K. Vishwakarma, Sandeep Kumar, Muniappan Sankar, Sachin Kumar Srivastava*, Kretschmann configuration based SPR sensor for the detection of cyanide ions in wastewater, Microchemical Journal 215 (2025) 114351
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Reena Jangra, Amritha J. Nair, Albin Kuriakose, Jitendra Nath Acharyya, G. Vijaya Prakash * and Muniappan Sankar * , Electron deficient β-trisubstituted porphyrins: synthesis, structural, spectral, and electrochemical studies and their intensity-dependent third-order nonlinear optical properties, Dalton Trans., 2025, 54, 10234
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Sumit Kumar Yadav, Naveen Kumar and Muniappan Sankar*, Oxidovanadium(IV) Porphyrin-Imidazole Complex-Catalyzed One-Pot, Three-Component Green Synthesis of Biologically Active Pyrano[2,3-d]pyrimidine and 4H-Chromene Heterocycles, Inorg. Chem. 2025, 64, 11907−11924
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Shivani Rathi, Ikrar Ahmad and Muniappan Sankar *, Unveiling the potential of tailored b-substituted iron-porphyrins for highly efficient oxygen reduction reactions (ORR), Chem. Commun., 2025, 61, 8512–8515
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Reena Jangra and Muniappan Sankar* , Synthesis, structural, spectral and electrochemical studies of β-acetamide appended porphyrins Journal of Porphyrins and Phthalocyanines 2025, 29, 124–133
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Nivedita Rana, Pankaj Kumar Chaudhary, Ramasare Prasad, and Muniappan Sankar* , Photodynamic Evaluation of A2BC Aminoporphyrins: Synthesis, Characterization, and Cellular Impact, ACS Appl. Bio Mater. 2025, 8, 5098−5108
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Pradeep Singh Thakur, Varsha Singh, Vellaichamy Ganesan and Muniappan Sankar*, Porphyrin-Based Covalent Organic Framework Encapsulating Multiwalled Carbon Nanotubes: A High-Performance Electrocatalyst for Oxygen Reduction Reaction , Langmuir 2025, 41, 10456−10468
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Pradeep Singh Thakur and Muniappan Sankar*, Fe-porphyrin-derived carbon nanofiber-based nanozymes: enhanced peroxidase-like activity for ultrasensitive glucose and ascorbic acid sensing, Mater. Adv., 2025, 6, 2356–2364
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V. Bhardwaj and M. Sankar*, Synthesis, Spectral, and Electrochemical Studies of Electron-Deficient Nitrile Porphyrins and the Utilization in Selective Cyanide Sensing, Dalton Trans.2025, 54,in press.
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A. S. Bulbul, J.Mogilipuri, S. V. Rao, and M. Sankar*, Meso-β, β–β’ trifused porphyrins: synthesis, spectral, electrochemical and DFT studies and their femtosecond third-order nonlinear optical properties, Dalton Trans.2025, 54,DOI: 10.1039/d4dt02930e.
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N. Rana, S. Kumariand M. Sankar* ‘Effect of Protonation-Induced Distortions on the Spectral Properties and Electronic Structure of Octaphenylporphyrins through UV-Vis and VT-NMR Spectral, Electrochemical and Ab Initio Studies‘Chem. Asian J.2024, 19, e202400719.
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A. S. Bulbul, R. Jangra, A. Kuriakose, J. N. Acharyya,G. V. Prakash and M. Sankar*‘Meso-β Monofused Porphyrins: Synthesis, Structural, Spectral, Electrochemical and DFT Studies and Their Efficient Third-Order Nonlinear Optical Properties’ Chem. Eur. J. 2024, 30, e202403473.
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R. Kumar, P. K. Chaudhary, R. Prasad and M. Sankar* ‘Utilization of Tin(IV) Complex of N-Confused Porphyrin for Antiproliferative Activity and Antimicrobial Photodynamic Chemotherapy, Chem. Asian J.2024, 19, e202401027.
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M. Tasleem, I. Ahmad and M. Sankar* ‘Porphyrin‐Based Covalent Organic Polymer Wrapped MWCNT Electrodes under Moderate Salt Concentration for Super‐Stable Aqueous Sodium‐Ion Intercalated Sustainable Supercapacitor’ Small 2024, 2409580.
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I. Yadav, D. Dhiman and M. Sankar* ‘Recent Advances in the Functionalization of Formyl and Acroleyl Appended Corroles’ Chem. Commun. 2024,60, 13456-13467 (Highlighted in the cover page of the journal).
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R. Kumar, V. Prakash and M. Sankar* ‘Synthesis of Vanadyl Complexes of N-Confused Porphyrins and Their Bromoperoxidase-like Catalytic Activity’ Inorg. Chem. 2024, 63, 12506–12515.
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S. Kumar, A. Patter and M. Sankar* ‘Enhanced Catalytic Activity of Binuclear Oxidovanadium(IV) Bisbenzimidazole Linked Porphyrin Dimer for the Generation of Biologically Active 3,4-Dihydropyrimidinones and Their Corresponding Thiones’ Inorg. Chem. 2024, 63, 11102–11112.
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M. Tasleem, V. Singh, A. Bansal, V. Ganesan and M. Sankar*‘Electrocatalysis Using Cobalt Porphyrin Covalently Linkedwith Multi-Walled Carbon Nanotubes: Hydrazine Sensingand Hydrazine-Assisted Green Hydrogen Synthesis’ Small 2024, 2401273.
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Francis D’Souza, M. Sankar and coworkers ‘Electrocatalytic Dinitrogen Reduction to Ammonia Using Easily Reducible N-Fused Cobalt Porphyrins’ Chem. Eur. J. 2024, 30, e202402610(Highlighted in the cover page of the journal).
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M. Tasleem, P. Chaudhry, R. Prasad and M. Sankar* ‘Synthesis and Characterization of Porphyrin-MWCNT Nanohybrid and its Utilization as an Antimicrobial Agent against S. aureus and E. coli’J. Porphyrins Phthalocyanines 2024, 28, 308-317.
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S. Kumari, V. Prakash, M. R. Maurya and M. Sankar* ‘The Synthesis of Highly Nonplanar Oxidovanadium(IV) Porphyrins as Robust Catalysts for Oxidative Bromination of Phenols in Aqueous Medium’ J. Porphyrins Phthalocyanines 2024, 28, 225-235.
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A. S. Bulbul, V. Rathour, V. Ganesan and M. Sankar*‘π-Extended nonplanar cobalt porphyrins immobilized on MWCNTs as efficient electrocatalysts for selective oxygen reduction reaction’ Chem. Commun. 2024,60, 3146-3149 (Selected for the cover page illustration).
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M. R. Maurya, V. Prakash and M. Sankar*‘Trans‐Dioxidomolybdenum(VI) Porphyrins and their Catalytic Activity Mimicking Oxidative Bromination’ Eur. J. Inorg. Chem. 2024, 27, e202400001.
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S. Kumari, V. Prakash, Siddharth S, M. R. Maurya andM. Sankar*‘Synthesis, Structural and Redox Properties of Vanadyl β-Cyanoporphyrin and its Utilization as Efficient Catalyst for Epoxidation of Olefins and Oxidative Bromination of Phenol‘Eur. J. Inorg. Chem. 2024, 27, e202300718.
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M. R. Maurya, V. Prakash F. Avecilla and M. Sankar*‘Facile Synthesis of β- Brominated Manganese Porphyrins and their Catalytic Potentials for Haloperoxidases-Like Activity‘Eur. J. Inorg. Chem. 2024,27, e202300708.
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A. K. Deval and M. Sankar* ‘Structural, photophysical, and electrochemical redox properties of meso-tetrakis(pentafluorophenyl)porphyrins‘J. Porphyrins Phthalocyanines 2024, 28, 87-106.
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A. Shukla, S. Kumari, M. Sankar, M. S. Nair ‘Insights into the Mechanism of Binding of Doxorubicin and a Chlorin Compound with 22-mer c-Myc G Quadruplex’ BBA-Gen. Sub. 2023, 1867, 130482.
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I. Yadav and M. Sankar* ‘Panchromatic and Perturbed Absorption Spectral Features and Multiredox Properties of Dicyanovinyl- and Dicyanobutadienyl-Appended Cobalt Corroles’ Inorg. Chem. 2023, 62,19956–19970.
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I. Yadav, V. Prakash, R. R. Kaswan, M. R. Maurya and M. Sankar* ‘Highly Efficient β-Functionalized Oxidomolybdenum(V) Corroles for Catalytic Oxidative Bromination of Phenols at Room Temperature’ Eur. J. Inorg. Chem. 2023, 26, e202300459.
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M. R. Maurya, V. Prakash, I. Yadav and M. Sankar* ‘Effect of para-Substituents on meso-Functionalized Oxidovanadium(IV) Porphyrins as Catalysts for Oxygen Atom Transfer Mediated Oxidation of Benzoin to Benzil under Mild Conditions’ Eur. J. Inorg. Chem. 2023, 26, e202300374.
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M. Shanu, J. N. Acharyya,M. Sankar* and G. V. Prakash,Enhanced Femtosecond Nonlinearities and Multiphoton Absorptions in Discrete Bands of Porphyrins, Inorg. Chem. 2023, 63, 12895-12094.
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I. Yadav, J. K. Sharma,M. Sankar* and F. D’Souza, Symmetrically Functionalized Copper and Silver Corrole-Bis-Tetracyanobutadiene Push-Pull Conjugates: Efficient Population of Triplet States via Charge Transfer, Chem. Eur. J. 2023, 29, e202301341 (Highlighted in the cover page of the journal).
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R. K. Rohal, D. Banerjee, T. Manchanda, V. Bhardwaj, S. V. Rao, and M. Sankar*, Synthesis and the Spectral, Electrochemical, and Nonlinear Optical Properties of β-Dicyanovinyl-Appended ‘Push-Pull’ Porphyrins, Dalton Trans.2023, 52, 5523-5533.
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S. Kumari, I. Yadav, M. Shanu, J. N. Acharyya, G. V. Prakash, and M. Sankar*, Push–pull octaphenylporphyrins with mixed substituents pattern: Synthesis, redox, ultrafast dynamics and nonlinear optical studies,Dyes and Pigments 2023, 217, 111416.
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I. Yadav, W. R. Osterloh, K. M. Kadish and M. Sankar*, Synthesis, Spectral, Redox, and Sensing Studies of β‑Dicyanovinyl-Appended Corroles and Their Metal Complexes, Inorg. Chem.2023, 63, 7738-7752.
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I. Yadav, V. Prakash, M. R. Maurya and M. Sankar*, Oxido-Molybdenum(V) Corroles as Robust Catalysts for Oxidative Bromination and Selective Epoxidation Reactions in Aqueous Media under Mild Conditions, Inorg. Chem.2023, 63, 5292-5301.
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P. Rathi, K. Prakash and M. Sankar*, β-Functionalized Palladium(II) Porphyrins: Facile Synthesis, Structural, Spectral, and Electrochemical Redox Properties, J. Porphyrins Phthalocyanines 2023, 27, 201-208(Invited Article on the occasion of 70th Birthday of Prof. Tomas Torres).
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M. R. Maurya, V. Prakash, F. Avecilla and M. Sankar*, Facile Synthesis of β‑Tetracyano Vanadyl Porphyrin from Its Tetrabromo Analogue and Its Excellent Catalytic Activity for Bromination and Epoxidation Reactions, ACS Omega.2023, 8, 6391-6401.
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M. R. Maurya, V. Prakash, I. Yadav and M. Sankar*,Effect of para-Substituents on Meso-Functionalized Oxidovanadium(IV) Porphyrins as Catalysts for Oxygen Atom Transfer Mediated Oxidation of Benzoin to Benzil under Mild Conditions, Eur. J.Inorg. Chem.2023, e202300374.
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M. Tasleem, V. Singh, V. Ganesan and M. Sankar*, Co(II) Porphyrin-MWCNT Nanoconjugate as an Efficient and Durable Electrocatalyst for Oxygen Reduction Reaction,Langmuir 2023, 39, 8075-8082.
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Yadav, M. Shanu, J. N. Acharyya, G. V. Prakash, and M. Sankar*, Ultrafast Dynamics and Strong Two-Photon Absorption Properties of Nonplanar β‑Functionalized “Push−Pull” Copper Corroles with a Mixed Substituent Pattern, Inorg. Chem.2022, 61, 9968-9982.
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K. Prakash and M. Sankar*, β-Diformyl porphyrins: Synthesis, structural, spectral and electrochemical properties, J. Porphyrins Phthalocyanines 2022, 26, 862-871.
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A. S. Bulbul, N. Chaudhri, M. Shanu, J. N. Acharyya, G. V. Prakash, and M. Sankar*, Unsymmetrically β-Functionalized π-Extended Porphyrins: Synthesis, Spectral, Electrochemical Redox Properties, and their Utilization as Efficient Two-Photon Absorber, Inorg. Chem.2022, 61, 9968-9982.
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R. K. Rohal, J. N. Acharyya, M. Shanu, G.V. Prakash and M. Sankar*, β-Tetracyanobutadiene Appended Porphyrins: Facile Synthesis, Spectral, and Electrochemical Redox Properties, and Their Utilization as Excellent Optical Limiters, Inorg. Chem. 2022, 61, 1297-1307 (Highlighted in the cover page of the journal).
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R. K. Rohal, J. N. Acharyya, M. S. Shanu, G. V. Prakash, and M. Sankar*, Synthesis and the Spectral, Electrochemical, and Nonlinear Optical Properties of β-Dicyanovinyl-Appended ‘Push-Pull’ Porphyrins. Dalton Trans.2022, 51, 9049-9061.
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P. S. Thakur V. Ganesan and M. Sankar*, Zn(II) Porphyrin-based Polymer Facilitated Electrochemical Synthesis of Green Hydrogen Peroxide, J. Electroanal. Chem. 2022, 919, 116536.
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P. S. Thakur and M. Sankar*, Nanobiosensors for Biomedical, Environmental, and Food Monitoring Applications, Mater. Lett. 2022, 311,131540.
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A. Jha, H. Shankar, S. Kumar, M. Sankarand P. Kar, Efficient charge transfer from organometal lead halide perovskite nanocrystals to free base meso-tetraphenylporphyrins. Nanoscale Advances2022, 4, 1779-1785.
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M.R. Maurya, V. Prakash and M. Sankar*, Selective epoxidation of olefins by vanadylporphyrin [V(IV)O(TPP)] and electron-deficient nonplanar β-octabromovanadylporphyrin [V(IV)O(TPPBr8)], J. Porphyrins Phthalocyanines 2022, 26, 187-194.
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S. Kumar, N. Chaudhri, W. R. Osterloh, K. M. Kadish and M. Sankar*, Nickel(II) monobenzoporphyrins and chlorins: synthesis, electrochemistry, and anion sensing properties, Dalton Trans. 2021, 50, 17086–17100.
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K. Prakash, W.R. Osterloh, P. Rathi, K.M. Kadish and M. Sankar*, Facile synthesis of antipodal β-arylaminodibromoporphyrins through Buchwald-Hartwig C-N coupling reaction and exploring their spectral and electrochemical redox properties, J. Organomet. Chem. 2021, 956, 122114.
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M. R. Maurya, V. Prakash, F. Avecilla and M. Sankar*, Selective Bromination of β‐Positions of Porphyrin by Self‐Catalytic Behaviour of VOTPP: Facile Synthesis, Electrochemical Redox Properties, and Catalytic Application, Eur. J. Inorg. Chem. 2021, 1685-1694.
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I. Yadav, D. Dhiman and M Sankar*, β-Disubstituted silver(III) corroles: Facile synthesis, photophysical and electrochemical redox properties. J. Porphyrins Phthalocyanines2021, 25, 547-554(Invited Article on the occasion of 65thBirthday of Prof. T. K. Chandrashekar).
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S. Kumar, J. N. Acharyya, D. Banerjee, V. R. Soma, G. V. Prakash, M. Sankar*, Strong Two-photon Absorption and Ultrafast Dynamics in Meso-Functionalized‟ Push-Pull” Trans-A2BC Porphyrins. Dalton Trans. 2021, 50, 6256-6272.
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D Tripathi, I Yadav, H Negi, RK Singh, VC Srivastava and M. Sankar*, Highly efficient Co(II) porphyrin catalysts for the extractive oxidative desulfurization of dibenzothiophene in fuel oils under mild conditions. J. Porphyrins Phthalocyanines2021, 25, 24-30.
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T. Anand and M Sankar*,A dual Colorimetric Chemosensor for Hg(II) and Cyanide ions in Aqueous Media based on a Nitrobenzoxadiazole (NBD)–Antipyrine Conjugate with INHIBIT Logic Gate behaviour. Anal. 2020, 19, 4526-4533.
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T. A. Dar and M Sankar*, Fused Nickel(II) Porphyrins for Sensing of Toxic Anions and Selected Metal Ions Through Supramolecular Interactions. Front. Chem. 2020, 8, 1050.
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W. R. Osterloh, S Kumar, N Chaudhri, Y Fang, M. Sankar*and KM Kadish, Facile Heterogeneous and Homogeneous Anion Induced Electrosynthesis: An Efficient Method for Obtaining π-Extended Porphyrins. Inorg. Chem.2020, 59, 16737-16746.
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P. Rathi, Ekta, S. Kumar, D. Banerjee, S. V. Rao and M. Sankar,* “Unsymmetrical β-Functionalized ‘Push-Pull’ Porphyrins: Synthesis, Photophysical, Electrochemical and Nonlinear Optical Properties”, Dalton Trans.2020, 49, 3198-3208.
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N. Chaudhri, L. Cong, A. S. Bulbul, N. Grover, W. R. Osterloh, Y. Fang, M. Sankar*and K. M. Kadish, “Structural, Photophysical, and Electrochemical Properties of Doubly Fused Porphyrins and Related Fused Chlorins”, Inorg. Chem. 2020, 59, 1481-1495.
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M. Sankar*, P. Rathi, A. Ganesan, S. Seetharaman, P. A. Karr and F. D'Souza “A Persubstituted Triphenylamine Bearing Dendritic Zinc Porphyrin to Host Endohedral Fullerene, Sc3N@C80: Formation and Excited State Electron Transfer”, J. Phys. Chem. B 2020, 124, 5723-5729.
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P. Rathi, Ekta, S. Kumar, D. Banerjee, S. V. Rao and M. Sankar,* “Unsymmetrical β-Functionalized ‘Push-Pull’ Porphyrins: Synthesis, Photophysical, Electrochemical and Nonlinear Optical Properties”, Dalton Trans.2020, 49, 3198-3208.
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N. Chaudhri, L. Cong, A. S. Bulbul, N. Grover, W. R. Osterloh, Y. Fang, M. Sankar* and K. M. Kadish, “Structural, Photophysical, and Electrochemical Properties of Doubly Fused Porphyrins and Related Fused Chlorins”, Inorg.Chem. 2020, 59, 1481-1495.
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N. Grover and M. Sankar*“N-Confused Porphyrin - A Unique “Turn on” and “Turn off” Anion Sensor” Chem. Asian J.2020, 15, 2192-2197.
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Y. Fang,§ I. Yadav,§ W. R. Osterloh, N. Chaudhri, M. Sankar*and K. M. Kadish, “Electrochemistry of Tri-substituted Porphyrins with β-Appended Ethyl Acetoacetate and Acetylacetone in Neutral and Basic Nonaqueous Solvents”, ChemElectroChem 2020, 7, 1723-1732. (§these authors contributed equally to this work).
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M. Yadav, P. K. Sonkar, K. Prakash , V. Ganesan, M. Sankar*, D. K. Yadav and R. Gupta “Insight into efficient bifunctional catalysis: Oxygen reduction and oxygen evolution reactions using MWCNTs based composites with 5,10,15,20-tetrakis(3′,5′-dimethoxyphenyl)porphyrinatocobalt(II) and 5,10,15,20-tetrakis(3′,5′-dihydroxyphenyl)porphyrinatocobalt(II)” Int. J. Hydrog. Energy 2020, 45, 9710-9722.
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T. A. Dar, A. S. Bulbul, M. Sankar*and K. M. Kadish, “Meso-Tetrapyrenyl- porphyrins: Synthesis, Structural, Spectral, and Electrochemical Properties and Förster Energy Transfer (FRET) Studies” J. Porphyrins Phthalocyanines 2020, 24, 985-992 (Invited Article on the occasion of 60thBirthday of Prof. Roberto Paolesse).
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W. R. Osterloh, Y. Fang, N. Chaudhri, L. Cong, M. Sankar*and K. M. Kadish,Effect of Fused Indanedione (IND) groups and Antipodal β-Substituents on Electrochemical Properties of Unsymmetrical Metalloporphyrins, J. Porphyrins Phthalocyanines 2020, 24, 1155-1165.
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N. Grover, N. Chaudhri and M. Sankar,* “β-Functionalized Dibenzoporphyrins with Mixed Substitutents Pattern: Facile Synthesis, Structural, Spectral and Electrochemical Redox Properties”, Inorg. Chem. 2019, 58, 2514-2522.
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P. Rathi, R. Butcher and M. Sankar,* “Unsymmetrical Nonplanar ‘Push-Pull’ β-Octa- substituted Porphyrins: Facile Synthesis, Structural, Photophysical and Electrochemical Redox Properties”, Dalton Trans. 2019, 48, 15002-15011 (Highlighted in the back cover of the journal).
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L. Cong§, M. K. Chahal§, R. Osterloh, M. Sankar*and K. M. Kadish, “Synthesis, Electrochemistry, and Reversible Interconversion among Perhalogenated Hydroxyphenyl Ni(II) Porphyrins, Porphodimethenes, and Porpho-5,15-bis-paraquinone Methide”, Inorg. Chem. 2019, 58, 14361-14376 (§these authors contributed equally to this work).
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T. A. Dar, B. Uprety, M. Sankar*and M. R. Maurya, “Robust and Electron Deficient Oxidovanadium(IV) Porphyrin Catalyst for Selective Epoxidation and Oxidative Bromination Reactions in Aqueous Media”, Green Chem., 2019, 21, 1757-1768.
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K. Prakash, A. Z. Alsaleh, Neeraj, P. Rathi, A. Sharma, M. Sankar*and F. D’Souza, “Synthesis, Spectral, Electrochemical and Photovoltaic Studies of A3B Porphyrinic Dyes having Peripheral Donors”, ChemPhysChem2019, 20, 2627-2634 (An invited article to a Special Issue on Solar Cells).
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K. Prakash, M. Sankar,* S. Seetharaman, and F. D’Souza, “Synthesis, Electrochemical and Photochemical Studies on π-Extended Mono-β-Functionalized Porphyrin Dyads”, ChemPhotoChem. 2019, 3, 151-165.
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N. Grover, N. Chaudhri and M. Sankar,* “β-Substituted Donor-Acceptor Porphyrins: Synthesis, Energy Transfer and Electrochemical Redox Properties”, Dyes Pigm. 2019, 161, 104-112.
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K. Prakash, V. Sudhakar, K. Krishnamoorthy and M. Sankar,* “Trans-A2B2ZnII-Porphyrin Dyes with Various Donor Groups and their Co-sensitization for Highly Efficient Dye Sensitized Solar Cells”, Dyes Pigm. 2019, 160, 386-394.
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M. Sankar and P. Bhyrappa, “Effect of Solvent on the Electronic Absorption Spectral Properties of Ni(II) and Cu(II)-complexes of Some Mixed β-Octasubstituted-meso- tetraphenylporphyrins”, Chem. Phys. Lett. 2019, 730, 643-648.
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T. A. Dar, R. Tomar, R. M. Mian, M. Sankar* and M. R. Maurya, “Vanadyl β-tetrabromoporphyrin: Synthesis, Crystal Structure and its use as an Efficient and Selective Catalyst for Olefin Epoxidation in Aqueous Medium” RSC Adv. 2019, 9, 10405-10413.
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N. Chaudhri, L. Cong, N. Grover, W. Shan, K. Ansul, M. Sankar*and K. M. Kadish, “Synthesis and Electrochemical Characterization of Acetylacetone (acac) and Ethyl Acetate (EA) Appended β-Trisubstituted Push-Pull Porphyrins: Formation of Electronically Communicating Porphyrin Dimers”, Inorg. Chem. 2018, 57,13213-13224.
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R. Kumar, V. Sudhakar, K. Prakash, K. Krishnamoorthy and M. Sankar,* “Tuning the Photovoltaic Performance of DSSCs by Appending Various Donor Groups on Trans- Dimesityl Porphyrin Backbone”, ACS Appl. Energy Mater. 2018, 1, 2793-2801 (One of the Most Read articles during May-July 2018).
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N. Chaudhri, N. Grover and M. Sankar,* “Nickel Induced Skeletal Rearrangement of Free Base trans-Chlorins into MonofusedNiII-Porphyrins: Synthesis, Structural, Spectral and Electrochemical Redox Properties”, Inorg. Chem. 2018, 57, 11349-11360.
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N. Chaudhri, N. Grover and M. Sankar,* “Selective Conversion of Planar trans-Chlorins into Highly Twisted Doubly Fused-Porphyrins or -Chlorins via Oxidative Fusion”, Inorg. Chem. 2018, 57, 6658-6668.
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X. Ke, R. Kumar, M. Sankar*and K. M. Kadish, “Electrochemistry and Spectroelectrochemistry of Cobalt Porphyrins with π-Extending and/or Highly Electron-Withdrawing Pyrrole Substituents. In Situ Electrogeneration of σ-Bonded Complexes”, Inorg. Chem. 2018, 57, 1490-1503.
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U. Sah, K. Sharma, N. Chaudhri, M. Sankar*and P. Gopinath, “Antimicrobial Photodynamic Therapy: Single-walled Carbon Nanotube (SWCNT)-Porphyrin Conjugate for Visible Light Mediated Inactivation of Staphylococcus aureus” Colloids and Surfaces B: Biointerfaces2018, 162, 108-117.
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N. Chaudhri, R. J. Butcher and M. Sankar,* “Synthesis, Structural, Photophysical, Electrochemical Redox and Axial Ligation Properties of Highly Electron Deficient Perchlorometalloporphyrins and Selective CN– Sensing by Co(II) Complexes”, New J. Chem. 2018, 42, 8190-8199 (Invited article for the themed issue on‘Equilibrium Solution Coordination Chemistry’).
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M. K. Chahal, T. A. Dar and M. Sankar,* “Facile Synthesis of Functionalized Urea, Imidazolium Salt, Azide and Triazole from 2-Amino-5,7-Dimethyl-1,8-Naphthyridine Scaffold and their Utilization in Fluoride ion Sensing”, New J. Chem. 2018, 42, 10059 -10066.
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N. Grover, R. Kumar, N. Chaudhri, R. Butcher and M. Sankar,* “β‐Heptasubstituted Porphyrins: Synthesis, Structural, Spectral and Electrochemical Redox Properties”, Eur. J. Inorg. Chem. 2018, 3338-3343.
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T. A. Dar, Mandeep and M. Sankar,* “Synthesis, Spectral and Elelctrochemical Redox Properties of N-Methyl Fused Nickel(II) Porphyrin” J. Porphyrins Phthalocyanines 2018, 22, 1106-1110.
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P. Bhyrappa and M. Sankar, “Effect of solvent on the electronic absorption spectral properties of some mixed β-octasubstitutedZn(II)-tetraphenylporphyrins”, Spectrochim. Acta A, 2018, 189, 80-85.
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P. Bhyrappa and M. Sankar, “Highly Nonplanar Macrocyclic Ring Conformation in the Crystal Structures of Ni(II) And Cu(II) Octaphenylporphyrins”, J. Struct. Chem. 2018, 59, 415-424.
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P. K. Sonkar, M. Yadav, K. Prakash, V. Ganesan, M. Sankar, D. K. Yadav and R. Gupta, “Electrochemical sensing of rifampicin in pharmaceutical samples using meso-tetrakis(4- hydroxyphenyl)porphyrinatocobalt(II) anchored carbon nanotubes”, J. Appl. Electrochem. 2018, 48, 937-946.
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N. Chaudhri, N. Grover and M. Sankar,* “Versatile Synthetic Route for β-Functionalized Chlorins and Porphyrins by Varying the Size of Michael Donors: Syntheses, Photophysical & Electrochemical Redox Properties”, Inorg. Chem. 2017, 56, 11532-11542 (Highlighted at Inorg. Chem. journal site as HOT paper).
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M. K. Chahal &M. Sankar,* “β-Dicyanovinyl Substituted Porphyrinogen: Synthesis, Reversible Sensor for Picric Acid among Explosives and Unique Sensor for Cyanide and Fluoride ions by Switching between Various Porphyrinoid States”, Dalton Trans. 2017, 46, 11669-11678 (Highlighted by RSTV and leading Newspapers inIndia).
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P. Rathi, M. K. Chahal and M. Sankar,* “Highly Electron Deficient Tetrabenzo- quinone Appended Ni(II) and Cu(II) Porphyrins: Spectral, Solvatochromism, Electrochemical Redox and Tuneable F‒ and CN‒ Sensing Properties”, New J. Chem. 2017, 41, 11962- 11968.
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X. Ke, P. Yadav, L. Cong, R. Kumar, M. Sankar* and K. M. Kadish, “Facile and Reversible Electrogeneration of Porphyrin Trianions and Tetraanions in Nonaqueous Media from Electron Deficient β-Substituted Porphyrins”, Inorg. Chem. 2017, 56, 8527- 8537.
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P. Yadav, M. Sankar,* X. Ke, L. Cong and K. M. Kadish, “Synthesis of π-Extended PhenylethynylCorroles and Their Intriguing Electrochemical Redox Properties”, Dalton Trans. 2017, 46, 10014-10022.
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P. Yadav, R. Kumar, A. Kumar and M. Sankar,* “Mixed Tri β-Substituted Push-Pull Porphyrins: Synthesis, Photophysical, Electrochemical and Theoretical studies”, Eur. J. Inorg. Chem. 2017, 3269-3274.
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M. K. Chahal, M. Sankar*and R. J. Butcher, “An Insight into Communication between β- olefin/phenyl olefin-mediated Acceptors and Porphyrin π-system: Way to establish Porphyrin based Chemodosimeters and Chemosensors”, Phys. Chem. Chem. Phys. 2017, 19, 4530-4540.
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K. Prakash, S. Manchanda, V. Sudhakar, N. Sharma, M. Sankar*and K. Krishnamoorthy, “Facile Synthesis of β-Functionalized ‘Push-Pull’ Zn(II) Porphyrin for DSSC Applications”, Dyes Pigm. 2017, 147, 56-66.
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P. Yadav, P. Rathi and M. Sankar,* “Facile Generation of A2B Corrole Radical and Its Spectroscopic Properties”, ACS Omega 2017, 2, 959-965.
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P. Yadav, M. S. S. Bharathi, S. Bhattacharya, M. Sankar*and S. V. Rao, “Synthesis and Femtosecond Third Order Nonlinear Optical Properties of Push-Pull Trans-A2B-Corroles”,Dyes Pigm. 2017, 143, 324-330.
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P. Yadav and M. Sankar,* “Spectroscopic and theoretical studies of anionic corroles derived from phosphoryl and carbomethoxyphenyl substituted corroles”, Chem. Phys. Lett. 2017, 667,107-113.
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T. A. Dar and M. Sankar,* “Facile Synthesis of Nitrovanillin Appended Porphyrin and Its Utilization as Potent, Recyclable, Naked-Eye CN− and F− Ion Sensor”, ChemistrySelect2017, 2,6778-6783.
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N. Chaudhri, N. Sawhney, B. Madhusudhan, A. Raghav, M. Sankar*and S. Satapati, “Effect of Functional Groups on Sensitization of Dye Sensitized Solar Cells using Free Base Porphyrins”, J. Porphyrins Phthalocyanines 2017, 21, 222-230.
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P. Sonkar, K. Prakash, M. Yadav, V. Ganesan, M. Sankar, R. Gupta and D. K. Yadav, “Co(II)-Porphyrins Decorated Carbon Nanotubes as Catalysts for Oxygen Reduction Reactions: An Approach for Fuel Cell Improvement”, J. Mater. Chem. A 2017, 5, 6263- 6276.
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N. Grover, N. Chaudhri and M. Sankar,*“Facile Conversion of Ni(II) Cyclopropyl- chlorins into Novelβ-Substituted Porphyrin through Acid-Catalyzed Ring-Opening Reaction”, Inorg. Chem. 2017, 56, 424-437.
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K. Prakash and M. Sankar,* “Borylated Porphyrin and its Metal Complexes: Synthesis, Elelcrochemistry and Deprotection-Protection Strategy for Anion Sensing”, Sensor and Actuators: B Chemical 2017, 240, 709-717.
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P. Yadav and M. Sankar,* “Facile synthesis, photophysical and electrochemical redox properties of octa- and tetra-carboxamidophenylporphyrins and the first example of amido- imidol tautomerism in porphyrins”, Dyes Pigm. 2017, 139, 351-357.
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M. K. Chahal and M. Sankar,* “Switching between Porphyrin, Porphodimethene and Porphyrinogen using Cyanide and Fluoride ions mimicking Volatile Molecular Memory and 'NOR' Logic Gate”, Dalton Trans. 2016, 45, 16404-16412.
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N. Grover, M. Sankar,* Y. Song and K. M. Kadish, “Asymmetrically Crowded ‘Push-Pull’ Octaphenylporphyrins with Modulated Frontier Orbitals: Syntheses, Photophysical and Electrochemical Redox Properties”, Inorg. Chem. 2016, 55, 584-597 (Highlighted as HOT PAPER and one of the most read article during Jan 2016).
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R. Kumar, M. Sankar,* V. Sudhakar and K. Krishnamoorthy, “Synthesis and Characterization of Simple Cost-effective Trans-A2BC-porphyrins with Various Donor Groups for Dye-Sensitized Solar Cells”, New. J. Chem. 2016, 40, 5704-5713 (an Invited article for the themed issue on Nitrogen Ligands).
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R. Kumar, A. Saxena and M. Sankar,* “Mixed β-Bromo/Cyano Tetrasubstituted-meso- Tetraphenylporphyrin Cu(II) Complexes: Synthesis and Electrochemical studies”, J. Porphyrins Phthalocyanines 2016, 20, 1420-1425.
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T. A. Dar, M. K. Chahal, A. Kumar and M. Sankar,* “Synthesis, Electrochemical andCompexation Studies of Zn(II) Aryloxyporphyrins with Fullerene C60”, J. Porphyrins Phthalocyanines 2016, 20, 744-751.
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M. K. Chahal and M. Sankar,* “Porphyrin Chemodosimeters: Synthesis, Electrochemical Redox Properties and Selective 'Naked-eye' Detection of Cyanide Ions”, RSC Adv. 2015, 5,99028-36.
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M. K. Chahal and M. Sankar,* “1,8-Naphthyridine-based Fluorescence Receptor for Picric Acid Detection in Aqueous Media”, Anal. Methods 2015, 7, 10272-1027914688 (One of the "Most accessed articles" during Nov2015).
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R. Kumar, N. Chaudhary, M. Sankar*and M. R. Maurya, “Electron Deficient Nonplanar β- Octachlorovanadylporphyrin as Highly Efficient and Selective Epoxidation Catalyst for Olefins”, Dalton Trans. 2015, 44, 17720-17729.
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R. Kumar, P. Yadav, P. Rathi and M. Sankar,* “Photophysical, electrochemical redox, solvatochromism and anion sensing properties of β-tetra- and -octaphenylethynyl substituted meso-tetraphenylporphyrins”, RSC Adv. 2015, 5, 82237-82246.
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K. Prakash, R. Kumar and M. Sankar,* “Mono- and Tri-β-Substituted Unsymmetrical Porphyrins: Synthesis, Structural, Spectral, and Electrochemical Properties”, RSC Adv. 2015, 5,66824-66832.
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N. Chaudhri, N. Grover and M. Sankar,* “Asymmetrically β-Substituted Porphyrins and Chlorins: Synthesis, Spectroscopic and Electrochemical Redox Properties”, ECS Trans. 2015, 66, 11-20 (Invited Article).
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R. Kumar, N. Chaudhri and M. Sankar,* “Naked eye Selective Detection of CN‒ ions by Electron Deficient Ni(II) Porphyrins and their Reversibility Studies”, Dalton Trans. 2015, 44, 9149-9157 (One of the "Most accessed articles" during April 2015).
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M. K. Chahal and M. Sankar,*“1,8-Naphthyridinic fluorescent ‘turn-on’ and ‘turn-off’ chemosensors for detecting of fluorideand Hg2+ ions mimicking INHIBIT molecular logic behavior”, Anal. Methods 2015, 7, 4552-59 (One of the “Most accessed articles” during May 2015).
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N. Grover, P. Rathi and M. Sankar,* “Spectral Investigations of Meso-tetraalkylporphyrin- C60host-guest complexes”, J. Porphyrins Phthalocyanines 2015, 19, 997-1006 (Selected for cover page illustration).
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R. Kumar, P. Yadav, A. Kumar and M. Sankar,* “Facile synthesis and electrochemical studies of diethoxy phosphorylphenyl substituted porphyrin and its metal complexes”, Chem. Lett. 2015, 44,914-916.
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N. Chaudhri and M. Sankar,* “Colorimetric Naked-eye detection of CN–, F–, CH3COO– and H2PO4–ions by highly nonplanar electron deficient perhaloporphyrins”, RSC Adv. 2015, 5,3269-3275.
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R. Kumar and M. Sankar,*“Synthesis, Spectral, and Electrochemical Studies of Electronically Tunable β-Substituted Porphyrins with Mixed Substituent Pattern”, Inorg. Chem. 2014, 53, 12706-12719.
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P. Yadav and M. Sankar,* “Synthesis, Spectroscopic and Electrochemical studies of Phosphoryl and Carbomethoxy Substituted Corroles and their Anion Detection Properties”, Dalton Trans. 2014, 43, 14680-14688 (One of the "Most accessed articles" during August2014).